Review on Nonoccupational Personal Solar UV Exposure Measurements

Solar ultraviolet (UV) radiation follows people during their whole life. Exposure to UV radiation is vital but holds serious risks, too. The quantification of human UV exposure is a complex issue. UV exposure is directly related to incoming UV radiation as well as to a variety of factors such as the orientation of the exposed anatomical site with respect to the sun and the duration of exposure. The use of badge-sensors allows assessing the UV exposure of differently oriented body sites. Such UV devices have been available for over 40 years, and a variety of measuring campaigns have been undertaken since then. This study provides an overview of those studies which reported measurements of the personal UV exposure (PE) during outdoor activities of people not related to their occupation. This overview is given chronologically to show the progress of knowledge in this research and is given with respect to different activities. Special focus is put on the ratio of personal exposure to ambient UV radiation. This ratio, when given as a function of solar elevation, allows estimating PE at any other location or date if ambient UV radiation is known

A method for an effective microclimate management in historical buildings combining monitoring and dynamic simulation: the case of “Museo Archeologico di Priverno”

In this work a method is proposed to estimate the effect of indoor microclimate on the risk of degradation of ancient materials stored in historical buildings. The method, which combines microclimate observations and dynamic simulation, has shown to be strategic in preventive conservation of historical buildings. Indeed, once the building model is calibrated, it can be effectively used for evaluating the microclimate control solutions on the conservation reducing general degradation risks. The method has been applied to a historical building close to Rome, where deteriorations in ceilings occurred and visitors complain about thermal discomfort. First, the HVAC system in the model has set in order to guarantee both thermal comfort and adequate condition for the conservation of the material. Then, the crack width of wooden ceiling has been estimated by means of an empirical model based on indoor temperature and relative humidity data and validated with the measurements of the crack width. It was found a reduction of annual variation from 0.4 mm to 0.2 mm, experimented by panels, and an improvement of maximum daily variation, especially in winter and summer (less than 0.01 mm on average)

CleAir monitoring system for particulate matter. A case in the Napoleonic Museum in Rome

Monitoring the air particulate concentration both outdoors and indoors is becoming a more relevant issue in the past few decades. An innovative, fully automatic, monitoring system called CleAir is presented. Such a system wants to go beyond the traditional technique (gravimetric analysis), allowing for a double monitoring approach: the traditional gravimetric analysis as well as the optical spectroscopic analysis of the scattering on the same filters in steady-state conditions. The experimental data are interpreted in terms of light percolation through highly scattering matter by means of the stretched exponential evolution. CleAir has been applied to investigate the daily distribution of particulate matter within the Napoleonic Museum in Rome as a test case

Optimising conservation of artworks, energy performance and thermal comfort combining hygrothermal dynamic simulation and on-site measurements in historic buildings

The indoor climate conditions being suitable for the conservation of cultural heritage can be conflicting with energy saving and thermal comfort. Moreover, the moisture dynamics have not been studied enough in the simulation of the indoor environment, even though its interaction with artworks is crucial in deterioration phenomena. This research aims at defining a strategy, based on experimental data and dynamic simulation of hygrothermal behaviour, in order to design a HVAC system able to simultaneously satisfy conservation, thermal comfort and energy requirements. A weighted function for the multi-objective optimization has been proposed and effectively used to pinpoint the combination of temperature and relative humidity set-points

Performance assessment of hygrothermal modelling for diagnostics and conservation in an Italian historical church

The hygrothermal modelling of historical churches is a promising approach to study preservation issues and suitable retrofit measures. However, difficulties can arise in the use of Heat, Air and Moisture (HAM) models, which are often customised objects to be integrated into validated building energy simulation (BES). This research outlines a multi-step methodology to investigate the capability of a BES software coupled with a HAM model (BES + HAM) as a technique for diagnostics and conservation in complex settings. The 17th-century church of Santa Rosalia (Italy) was used as a historical site in a real context. As first step, the performance of the simulation tool was analysed through standardised exercises aiming at excluding incorrect assumptions and calculations in the HAM model (HMWall). Secondly, a building model of the church using a 1D heat transfer model (named building model A) was compared with one using HMWall (named building model B) in terms of the accuracy of the indoor climate simulations against hygrothermal measurements. The results showed that building model B enhanced the simulation accuracy by +50% with respect to building model A. Finally, annual simulations inside the church were run to further compare the seasonal trends of indoor climate scenario obtained from the two building models. Building model B allowed to study the water content distribution inside the altarpiece and a wall partition, showing that BES + HAM tools can be used to identify potential moisture-induced conservation risks

Monitoring of solar spectral ultraviolet irradiance in Aosta, Italy

A Bentham DTMc300 spectrophotometer is deployed at the station of Aosta–Saint-Christophe, Italy, at the headquarters of the Regional Environmental Protection Agency (ARPA) and performs continuous high quality spectral measurements of the solar ultraviolet (UV) irradiance since 2006. The measuring site is located in the North-western of the Alps, in a large valley floor at the altitude of 570 m a.s.l., surrounded by mountains. It is very significant to have accurate measurements in such a sensitive environment, since the complex terrain and the strongly variable meteo-climatic conditions typical of the Alps induce large spatial and temporal variability in the surface levels of the solar UV irradiance. The spectroradiometer is moreover used as a reference of a regional UV network, with additional stations located at different altitudes (1640 and 3500 m a.s.l.) and environmental conditions (mountain and glacier). In the present study we discuss the procedures and the technical aspects which ensure the high quality of the measurements performed by the reference instrument, and subsequently of the entire network. In particular, we describe the procedures used to characterize the Bentham for its characteristics which affect the quality of the measurements. The used Quality Control/Quality Assurance (QA/QC) procedures are also discussed. We show that the good quality of the spectral measurements is further ensured by a strong traceability chain to the world reference QASUME and a strict calibration protocol. Recently, the spectral UV dataset of Aosta–Saint-Christophe has been re-evaluated and homogenized. The final spectra consist one of the most accurate datasets globally. At wavelengths above 310 nm and for solar zenith angles below 75° the expanded uncertainty in the final dataset decreases with time, from 7% in 2006 to 4% in the present. The present study not only serves as the reference document for any future use of the data, but also provides useful information for experiments and novel techniques which have been applied for the characterization of the instrument, and the QA/QC of the spectral UV measurements. Furthermore, the study clearly shows that maintaining a strong traceability chain to a reference instrument is critical for the good quality of the measurements. The studied spectral dataset is freely accessible at https://doi.org/10.5281/zenodo.3934324 (Fountoulakis et al., 2020)

Examination on total ozone column retrievals by Brewer spectrophotometry using different processing software

The availability of long-term records of the total ozone content (TOC) represents a valuable source of information for studies on the assessment of short-and long-term atmospheric changes and their impact on the terrestrial ecosystem. In particular, ground-based observations represent a valuable tool for validating satellite-derived products. To our knowledge, details about software packages for processing Brewer spectrophotometer measurements and for retrieving the TOC are seldom specified in studies using such datasets. The sources of the differences among retrieved TOCs from the Brewer instruments located at the Italian stations of Rome and Aosta, using three freely available codes (Brewer Processing Software, BPS; O3Brewer software; and European Brewer Network (EUBREWNET) level 1.5 products) are investigated here. Ground-based TOCs are also compared with Ozone Monitoring Instrument (OMI) TOC retrievals used as an independent dataset since no other instruments near the Brewer sites are available. The overall agreement of the BPS and O3Brewer TOC data with EUBREWNET data is within the estimated total uncertainty in the retrieval of total ozone from a Brewer spectrophotometer (1%). However, differences can be found depending on the software in use. Such differences become larger when the instrumental sensitivity exhibits a fast and dramatic drift which can affect the ozone retrievals significantly. Moreover, if daily mean values are directly generated by the software, differences can be observed due to the configuration set by the users to process single ozone measurement and the rejection rules applied to data to calculate the daily value. This work aims to provide useful information both for scientists engaged in ozone measurements with Brewer spectrophotometers and for stakeholders of the Brewer data products available on Web-based platforms

Investigation on the Use of Passive Microclimate Frames in View of the Climate Change Scenario

[EN] Passive microclimate frames are exhibition enclosures able to modify their internal climate in order to comply with paintings¿ conservation needs. Due to a growing concern about the effects of climate change, future policies in conservation must move towards affordable and sustainable preservation strategies. This study investigated the hygrothermal conditions monitored within a microclimate frame hosting a portrait on cardboard with the aim of discussing its use in view of the climate expected indoors in the period 2041¿2070. Its effectiveness in terms of the ASHRAE classification and of the Lifetime Multiplier for chemical deterioration of paper was assessed comparing temperature and relative humidity values simultaneously measured inside the microclimate frame and in its surrounding environment, first in the Pio V Museum and later in a residential building, both located in the area of Valencia (Spain). Moreover, heat and moisture transfer functions were used to derive projections over the future indoor hygrothermal conditions in response to the ENSEMBLES-A1B outdoor scenario. The adoption of microclimate frames proved to be an effective preventive conservation action in current and future conditions but it may not be sufficient to fully avoid the chemical degradation risk without an additional control over temperatureThis project received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No. 814624. This research was partially supported by the Plan Nacionalde I+D, Comision Interministerial de Ciencia y Tecnologia (FEDER-CICYT) under project HAR2013-47895-C2-1-P.Verticchio, E.; Frasca, F.; García Diego, FJ.; Siani, AM. (2019). Investigation on the Use of Passive Microclimate Frames in View of the Climate Change Scenario. Climate. 7(8):1-14. https://doi.org/10.3390/cli70800981147

Aerosol Single Scattering Albedo retrieval in the UV range: an application to OMI satellite validation

Abstract. The aerosol Single Scattering Albedo (SSA) and Absorbing Aerosol Optical Depth (AAOD) at 320.1 nm are derived at Rome site by the comparison between Brewer and modelled spectra. The UVSPEC radiative transfer model is used to calculate the UV irradiances for different SSA values, taking into account as input data total ozone and Aerosol Optical Depth (AOD) obtained from Brewer spectral measurements. The accuracy in determining SSA depends on the aerosol amount and on Solar Zenith Angle (SZA) value: SSA uncertainty increases when AOD and SZA decrease. The monthly mean values of SSA and AAOD during the period January 2005–June 2008 are analysed, showing a monthly and seasonal variability. It is found that the SSA and AAOD averages are 0.80±0.08 and 0.056±0.028, respectively. AAOD retrievals are also used to quantify the error in the Ozone Monitoring Instrument (OMI) surface UV products due to absorbing aerosols, not included in the current OMI UV algorithm. OMI and Brewer UV irradiances at 324.1 nm and Erythemal Dose Rates (EDRs) under clear sky conditions, are compared as a function of AAOD. Three methods are considered to investigate on the applicability of an absorbing aerosol correction on OMI UV data at Rome site. Depending on the correction methodology, the bias value decreases from 18% to 2% for spectral irradiance at 324.1 nm and from 25% to 8% for EDR

Novel Model Based on Artificial Neural Networks to Predict Short-Term Temperature Evolution in Museum Environment

The environmental microclimatic characteristics are often subject to fluctuations of considerable importance, which can cause irreparable damage to art works. We explored the applicability of Artificial Intelligence (AI) techniques to the Cultural Heritage area, with the aim of predicting short-term microclimatic values based on data collected at Rosenborg Castle (Copenhagen), housing the Royal Danish Collection. Specifically, this study applied the NAR (Nonlinear Autoregressive) and NARX (Nonlinear Autoregressive with Exogenous) models to the Rosenborg microclimate time series. Even if the two models were applied to small datasets, they have shown a good adaptive capacity predicting short-time future values. This work explores the use of AI in very short forecasting of microclimate variables in museums as a potential tool for decision-support systems to limit the climate-induced damages of artworks within the scope of their preventive conservation. The proposed model could be a useful support tool for the management of the museums